Concrete plasticizers are the mainstream products for
readymix facilities. They are widely used all over the world and for the moment
they are the number 1 admixture/additive as far as it regards the worldwide
consumption.
Others name used for this category of additives
are:
- normal water reducers
- water reducing additives/admixtures
- normal plasticizers etc.
Plasticizers are mostly based
on lignosulfonates. Lignosulfonates or sulfonated lignins are by -
products of the paper industry, recovered from the pulping liquids.
Lignosulfonates are usually modified with special polymers to mainly control air entrainment and setting times, or improve/regulate other parameters.
Other chemicals used are hydroxycarboxylic salts.
Plasticizers are considered to give water reductions at the region of 10%. A little more or a little less.
Lignosulfonates are usually modified with special polymers to mainly control air entrainment and setting times, or improve/regulate other parameters.
Other chemicals used are hydroxycarboxylic salts.
Plasticizers are considered to give water reductions at the region of 10%. A little more or a little less.
Usual dosages are between 0.25 – 0.8% by cement weight.
Example: a concrete mix with 350Kg cement/m3 can accept a
plasticizer quantity between 0.25 x 350/100 and 0.8x350/100 Kg/m3 or 0.875 –
2.8 Kg/m3.
The commonest dosages are in the range of 0.3-0.4% by
cement weight.
For each different project, product trials should be made
to conclude to an optimal dosage.
HOW DO PLASTICIZERS FUNCTION?
Cement particles tend to flocculate and the role of
plasticizers/water reducers is to induce deflocculation.
This is achieved by adsorption of their active
constituents onto the cement particles. Thus the surface charges on their
surface are neutralized and the cement flocs break up.
By this way the water that was tied up in the cement
flocs is released and used to reduce the viscosity of the mixture.
WHY ARE PLASTICIZERS USED?
Plasticizers are used for the following reasons:
1. To reduce the water content of the concrete by about
+/- 10%. This they achieve with their dispersing power and with
practically no alteration of the slump.
The water reduction will lead of course to increased
strengths.
2. To increase the slump/workability without changing the
ratio W/C. This will facilitate the placement of the concrete.
3. To achieve a compromise between the above.
4. To achieve economies in the mix design by reducing the
cement content without compromising the final strengths.
RETARDATION
Most of water reducers/plasticizers have
a retardation effect on the setting time of the concrete. This is
more pronounced when:
- the dosages are higher than those recommended
(overdosing)
- the temperatures are lower
- the synthesis contains polysaccharides.
OVERDOSING
Overdosing will induce setting retardation.
In case of severe overdosing – double quantity or more – additional
curing measures should be undertaken to prevent excessive drying on the surface
of the concrete.
CONCRETE STRENGTH
When plasticizers are used as water reducers, an increase
of about 7-10% of the compressive strength of 28 days can be expected.
Typically, early strength, will depend on water
reduction.
SLUMP/CONSISTENCY
The ability of the concrete to flow is called its consistency and slump is
a measure of consistency. If ratio W/C remains unaltered, the addition of a
plasticizer will increase concrete consistency and slump.
To delay the slump loss, the initial consistency should
be increased.
AIR ENTRAINING
Plasticizers/water reducers based on lignosulfonates tend
to induce some air entrainment in contract with hydroxycarboxylic salts.
OVERALL DURABILITY
The W/C is reduced the overall durability of the concrete
is increased.